The hydrosphere is the term geologists and chemists use for all the water found on, above, and below the surface of the Earth. It includes the water in oceans, ice caps and glaciers, groundwater stored underground, lakes and rivers, and even the water vapour suspended in the atmosphere. The hydrosphere interacts constantly with the other Earth systems — the atmosphere (air), lithosphere (rock and soil), and biosphere (living things) — making water central to almost every chemical and biological process on the planet.
Although Earth is often called the "blue planet" because roughly 71% of its surface is covered in water, the vast majority of that water is not usable by humans, plants, or land animals in its natural state. This is one of the most important — and most surprising — facts in environmental chemistry.
This means that the freshwater available to sustain all terrestrial life — every river, lake, dam, and accessible aquifer on Earth — makes up a tiny sliver of the planet's total water budget. This scarcity is why sustainable water management and water chemistry (purification, treatment, and conservation) are such critical fields of study.
| Water reservoir | Approx. % of total water | State |
|---|---|---|
| Oceans (saline) | ~97% | Liquid |
| Ice caps & glaciers | ~1.7% (≈69% of freshwater) | Solid |
| Groundwater | ~0.75% (≈30% of freshwater) | Liquid |
| Surface water (rivers, lakes) & atmosphere | <0.03% | Liquid / vapour |
Water continuously moves between the hydrosphere, atmosphere, and lithosphere in a cycle driven by solar energy and gravity. This is the water cycle (hydrological cycle), and it consists of five key processes:
Water is often called the "universal solvent" because its polar molecular structure allows it to dissolve more substances than any other common liquid. The oxygen atom in H₂O carries a partial negative charge (δ⁻) and the two hydrogen atoms carry partial positive charges (δ⁺). This polarity allows water molecules to surround and separate ions and other polar molecules, pulling them into solution.
This solvent property is essential to both biology and chemistry:
South Africa is classified as a water-scarce country. Rainfall is low and unevenly distributed (the national average is roughly half the global average), evaporation rates are high due to our warm climate, and there are few large natural lakes or major rivers compared to many other countries. As a result, South Africa relies heavily on a network of built dams to store surface water and on groundwater (aquifers) to supplement supply, particularly in drier regions such as the Karoo and parts of the Western and Northern Cape.
Events such as the Cape Town "Day Zero" drought crisis (2017–2018) highlighted how quickly a water-scarce country can approach the point where municipal water supplies run dry, underscoring the importance of conservation, reuse, and sound water chemistry in both households and industry.
Water hardness is caused by dissolved calcium (Ca²⁺) and magnesium (Mg²⁺) ions, typically picked up as groundwater passes through limestone or dolomite rock. Hard water reacts with soap to form an insoluble "scum" (a precipitate of calcium/magnesium stearate) rather than lathering easily, and on heating it can deposit solid calcium carbonate (CaCO₃) scale inside kettles, geysers, and pipes.
Typical municipal water treatment steps in South Africa include: (1) screening — removing large debris; (2) coagulation/flocculation — adding chemicals to clump fine suspended particles together; (3) sedimentation — allowing clumped particles to settle out; (4) filtration — passing water through sand/gravel beds to remove remaining particles; (5) disinfection — typically chlorination, to kill disease-causing microorganisms before the water is distributed.
Understanding these steps links directly to the ionic chemistry studied in this strand — coagulation, precipitation of impurities, and disinfection reactions are all governed by the same principles of solubility and reactions in aqueous solution covered earlier in this content area.
Click any segment of the bar to see its exact percentage and a short fact. Switch views to zoom from Earth's total water into just the freshwater slice.
| Month | Jan | Mar | May | Jul | Sep |
|---|---|---|---|---|---|
| Combined dam level (%) | 50 | 40 | 30 | 20 | 10 |