A physical change is a change in which the physical properties of a substance (state, shape, size, or appearance) alter, but no new substance is formed. The particles present before the change are exactly the same particles present after the change โ they have simply been rearranged, moved apart, moved closer together, or reshaped.
Common types of physical change:
A chemical change occurs when a chemical reaction takes place: the bonds between atoms in the reactants break, and new bonds form to create one or more new substances (products) with properties completely different from the original substances.
Common examples of chemical change: burning (combustion), rusting (corrosion), baking a cake, digestion of food, photosynthesis, a battery discharging, and milk turning sour.
Because you cannot always "see" a new substance directly, chemists look for observable clues (evidence) that a chemical reaction has probably occurred. On its own, no single clue is absolute proof โ but several of these together are strong evidence:
| Evidence | Description | Example |
|---|---|---|
| Colour change | The substance changes colour, indicating a new substance with different light-absorbing properties | Iron turning orange-brown as it rusts |
| Gas / bubbles produced | Effervescence or fizzing shows a gas is being released | Bubbles when vinegar reacts with baking soda |
| Precipitate forms | An insoluble solid suddenly appears in a solution that was clear | A white solid forming when two clear solutions are mixed |
| Temperature change | Energy is released (exothermic) or absorbed (endothermic) during the reaction | A fire feels hot; an instant cold-pack feels cold |
| Light produced | Energy is released as light | A sparkler burning, a firework exploding |
| Permanent / difficult to reverse | The change cannot easily be undone by physical means | You cannot "un-bake" a cake or "un-burn" wood |
| Feature | Physical Change | Chemical Change |
|---|---|---|
| New substance formed? | No | Yes |
| Chemical composition | Unchanged | Changed |
| Reversibility | Usually easy to reverse | Usually difficult / impossible to reverse |
| Energy change | Usually small | Often a noticeable temperature/light change |
| Example | Melting ice, dissolving salt | Burning wood, rusting iron |
Let's classify some everyday changes and explain why:
Energy profile of a reaction: Every chemical change involves an energy change. In an exothermic reaction, the products have less stored (chemical potential) energy than the reactants โ the difference is released as heat and/or light to the surroundings (e.g. combustion, respiration). In an endothermic reaction, the products have more stored energy than the reactants โ energy is absorbed from the surroundings, which cools down (e.g. photosynthesis, the reaction in an instant cold-pack).
Applying the concept: Consider baking a cake. The raw batter (reactants) undergoes several simultaneous chemical changes when heated: proteins denature, sugars caramelise (Maillard/browning reactions), and raising agents (e.g. baking powder) decompose to release COโ gas โ evidence: colour change (browning), gas produced (rising), and the change is permanent (you cannot "un-bake" a cake back into batter). This makes baking a rich real-world example combining several types of evidence for chemical change in a single process.
Distinguishing tricky cases: Some changes look chemical but are physical, and vice versa. Dry ice (solid COโ) "smoking" as it sublimes looks dramatic (mist, temperature drop) but is a physical change of state (sublimation) โ the COโ remains COโ. Conversely, a battery discharging shows no colour change or gas visible from outside, yet chemical reactions are occurring inside it (chemical energy is being converted to electrical energy) โ a chemical change with subtle external evidence.
| State | Mass (g) | Volume (cmยณ) |
|---|---|---|
| Ice (solid) | 90.0 | 98.0 |
| Water (liquid, after melting) | 90.0 | 90.0 |