Grade 9 · Matter & Materials · Lesson 4

Types of Chemical Reactions

Classify chemical reactions as synthesis, decomposition, single displacement, or double displacement — and practise balancing equations using conservation of mass.

What is a Chemical Reaction?

A chemical reaction occurs when substances (reactants) are transformed into new substances (products). The key principle is the Law of Conservation of Mass (Lavoisier): matter is neither created nor destroyed — the total mass of reactants equals the total mass of products.

Chemical equation format: Reactants → Products
Example: 2H₂ + O₂ → 2H₂O (atoms are balanced on both sides)

Balancing Equations

To balance an equation, only change the coefficients (numbers in front of formulas) — never change subscripts inside a formula. Count atoms on each side and adjust until they match.

Unbalanced: H₂ + O₂ → H₂O
Balanced: 2H₂ + O₂ → 2H₂O
Left: 4H, 2O · Right: 4H, 2O ✓

1. Synthesis (Combination) Reactions

Two or more reactants combine to form a single product: A + B → AB

Tip: the number of products is always ONE in a synthesis reaction.

2. Decomposition Reactions

A single compound breaks down into two or more simpler substances: AB → A + B. These reactions require energy input — heat, electricity, or light.

Tip: the number of reactants is always ONE in a decomposition reaction.

3. Single Displacement (Substitution) Reactions

A more reactive element displaces a less reactive element from a compound: A + BC → AC + B

The activity series ranks metals from most reactive (K, Na, Ca, Mg, Al, Zn, Fe, Ni, Sn, Pb, H, Cu, Ag, Au) to least reactive. A metal can only displace metals below it in the series.

Key rule: Fe displaces Cu because Fe is above Cu in the activity series. Cu cannot displace Fe.

4. Double Displacement (Exchange) Reactions

Two compounds exchange ions to form two new compounds: AB + CD → AD + CB. These often produce a precipitate (insoluble solid), a gas, or water.

Neutralisation is a special case of double displacement: acid + base → salt + water

5. Energy in Reactions

TypeEnergy changeTemperatureExamples
ExothermicReleases energy (heat)Surroundings get hotterCombustion, neutralisation, respiration
EndothermicAbsorbs energy (heat)Surroundings get coolerPhotosynthesis, decomposition, dissolving NH₄NO₃

6. Combustion (Oxidation-Reduction)

Combustion is the reaction of a fuel with oxygen, releasing heat and light. It is a type of redox reaction where carbon compounds are oxidised.

Complete combustion: CH₄ + 2O₂ → CO₂ + 2H₂O
Incomplete combustion: 2CH₄ + 3O₂ → 2CO + 4H₂O (carbon monoxide — toxic!)

Rate of Reaction

How quickly reactants are converted to products depends on:

Reaction Type Simulator

Reaction Type
Balanced Equation
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Answer the following questions in full sentences. Show all working for calculations. Use the lesson notes to help you.
Question 1
State the Law of Conservation of Mass and explain why it means we must balance chemical equations. Balance the following equation and identify the reaction type: Fe + O₂ → Fe₂O₃
Question 2
Classify each of the following reactions as synthesis, decomposition, single displacement, or double displacement. Briefly justify your answer in each case.
(a) 2KClO₃ → 2KCl + 3O₂
(b) Mg + 2HCl → MgCl₂ + H₂
(c) SO₃ + H₂O → H₂SO₄
(d) Pb(NO₃)₂ + 2KI → PbI₂ + 2KNO₃
Question 3
Using the activity series (K, Na, Ca, Mg, Al, Zn, Fe, Ni, Sn, Pb, H, Cu, Ag, Au), explain why zinc can displace copper from copper sulfate solution but copper cannot displace zinc from zinc sulfate solution. Write the balanced equation for the zinc/copper sulfate reaction.
Question 4
Distinguish between exothermic and endothermic reactions. Give two examples of each. Explain what happens to the temperature of the surroundings during each type and why.
Question 5
A learner grinds a calcium carbonate (marble) chip into a fine powder before adding it to hydrochloric acid. The reaction produces CO₂ gas.
(a) Write the balanced equation for this reaction and classify its type.
(b) Explain why the powdered marble reacts faster than the whole chip.
(c) Name two other factors that could increase the rate of this reaction and explain the reason for each.
Question 6
A learner reacts the SAME MASS of marble chips with excess hydrochloric acid in two separate experiments — one using large chips, one using powdered marble — and measures the volume of CO₂ gas collected at 20-second intervals:

Time (s)Gas volume — large chips (cm³)Gas volume — powdered marble (cm³)
000
201035
402258
603360
804560
1005560
1206060
(a) Plot both sets of data on the same set of axes (gas volume on the y-axis, time on the x-axis) to draw two rate-of-reaction graphs.

(b) At what time does each experiment stop producing gas (reach its maximum volume)?

(c) Both experiments eventually produce the SAME total volume of gas (60 cm³). Explain why the final volume is the same even though the reactions happen at different rates.

(d) Using the idea of surface area and particle collisions, explain why the powdered marble reaches its maximum gas volume so much faster than the large chips.